MATERIAL SAFETY DATA SHEET Date-Issued: 01/13/2000 MSDS Ref. No: 002784 Date-Revised: 02/27/2004 Revision No: 2 EVERCIDE® Permethrin 10% EC 2784 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: EVERCIDE® Permethrin 10% EC 2784 PRODUCT DESCRIPTION: A Long Lasting Livestock and Premise Spray PRODUCT CODE: 002784, EPA REG. NO. : 1021-1736 MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC U.S. and CANADA: (800) 424-9300 CHEMTREC All Other Areas: (703) 527-3887 Emergency Phone: (888) 740-8712 Product Stewardship: (763) 544-0341 Customer Service: (800) 645-6466 COMMENTS: MGK's Hours of operation are 8:00 am to 4:30 pm CST, 14:30 to 22:30 GMT.
For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call the INTERNATIONALPOISON CENTER 24 hours a day at 1-888-740-8712 . 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# EINECS # 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: CAUTION. OSHA-COMBUSTIBLE LIQUID. Do not use or store near heat, sparks,
open flame, or any other ignition sources. Harmful if swallowed or absorbed through the skin. Avoid contactwith skin, eyes, and clothing.
A full-faced gas mask with canister is recommended for general protection when applying indoors as a spacespray or fogger.
POTENTIAL HEALTH EFFECTS EYES: May cause eye injury. SKIN: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, SKIN ABSORPTION: Harmful if absorbed through the skin. INGESTION: Harmful if swallowed. INHALATION: Excessive inhalation of mists can cause nasal and respiratory irritation. CHRONIC: None known. 4. FIRST AID MEASURES EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment
EVERCIDE® Permethrin 10% EC 2784 SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a
poison control center or doctor for treatment advice. INGESTION: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT
give any liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to an unconscious person. INHALATION: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then
give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for furthertreatment advice. NOTES TO PHYSICIAN: Contains Pyrethroids, surfactants, and Petroleum Distillates - vomiting may pose an
For skin effects, a highly efficient therapeutic agent for Pyrethroid exposure is topical application of TocopherolAcetate (Vitamin E). 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: 61.1°C (142°F)TAG Closed Cup FLAMMABLE CLASS: OSHA-COMBUSTIBLE LIQUID EXTINGUISHING MEDIA: Use water spray, foam, carbon dioxide or dry chemical. HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions this product will support combustion and may
decompose to give off toxic gases such as Carbon Monoxide, Carbon Dioxide, and nitrogen oxides. Chlorinegas and Hyrdrogen Chloride may also be formed under fire conditions. FIRE FIGHTING PROCEDURES: Use a full-faced self-contained breathing apparatus along with full protective
gear. Keep nearby containers and equipment cool with a water stream. SENSITIVE TO STATIC DISCHARGE: Yes, use proper bonding and/or grounding procedures. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if
possible, and if immediate response can prevent further damage or danger. Isolate and control access to therelease area. Take actions to reduce vapors. Absorb with appropriate absorbent. Clean spill area of residuesand absorbent. LARGE SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if
possible, and if immediate response can prevent further damage or danger. Isolate and control access to therelease area. Take actions to reduce vapors. Collect product into drums, etc. via drains, pumps, etc. Absorbwith appropriate absorbent. Clean spill area of residues and absorbent. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Contains pyrethroids which are toxic to fish and other aquatic invertebrates. Contaminated
absorbent and wash water should be disposed of according to local, state/provincial and federal/nationalregulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Do not use near heat, open flame, or any other ignition source. HANDLING: Take prudent precautions to avoid contact with skin, eyes, and clothing. Mechanical ventilation
should be used when handling this product in enclosed spaces. Avoid breathing vapors or spray mists of this
EVERCIDE® Permethrin 10% EC 2784
product. Wearing a respirator is not normally required when handling this product, but recommended in theabsence of proper mechanical ventilation. Do not contaminate water, food or feedstuffs, by storage, handling,or by disposal. Read and observe all precautions and instructions on the label. STORAGE: Store in areas that are warm, dry, and well-ventilated. Store containers upright and closed. Do not
use or store near heat or open flame. Avoid exposure to extreme temperatures.
ELECTROSTATIC ACCUMULATION HAZARD: Use proper bonding or grounding procedures when handling 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) EXPOSURE LIMITS ACGIH TLV Supplier OEL ppm mg/m3 ppm mg/m3 ppm mg/m3 ENGINEERING CONTROLS: Mechanical ventilation should be used when handling this product in enclosed
spaces. Local exhaust ventilation may be necessary. Wear a respirator if product will be confined to indooruse. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Take prudent precautions to avoid contact with eyes. SKIN: Take prudent precautions to avoid contact with skin and clothing. RESPIRATORY: Take prudent precautions to avoid breathing vapors or spray mists of this product. Wear a
NIOSH-approved organic vapor respirator if this product will be confined to indoor use, or in absence ofproper mechanical ventilation. WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK
AREA!Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking,or using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Mild sweet odor with a hint of aromatics. APPEARANCE: Clear, amber-colored liquid. VAPOR PRESSURE: Not Available VAPOR DENSITY: Heavier than air. BOILING POINT: Not Available FREEZING POINT: Not Available SOLUBILITY IN WATER: Partially miscible in water. DENSITY: Not Available SPECIFIC GRAVITY: 0.843 (Water = 1) Hydrometer @ 20°C (68°F) (VOC): <52 % 10. STABILITY AND REACTIVITY EVERCIDE® Permethrin 10% EC 2784 STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: Not compatible with strong acids or bases. Not compatible with strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: May decompose under fire or extreme temperatures to give off
toxic Chlorine gas, Hydrogen Chloride, as well as Carbon Monoxide, Carbon Dioxide, and Nitrogen Oxides.
11. TOXICOLOGICAL INFORMATION DERMAL LD50: >2000 mg/kg ORAL LD50: >2000 mg/kg INHALATION LC50: The Acute Inhlation LC50 of this material places it in EPA Toxic Category III. EYE EFFECTS: Data not available. SKIN EFFECTS: No irritation observed. Irritation Index = 0.0 SENSITIZATION: Negative; Not considered to be a dermal sensitizer to albino guinea pigs. GENERAL COMMENTS: Some or all of the toxicity data reported above was bridged from a substantially similar COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1%
are listed by IARC, NTP, OSHA or ACGIH as being carcinogens. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Environmental data not available for this product. ECOTOXICOLOGICAL INFORMATION: This pesticide is extremely toxic to fish. Do not apply directly to water,
to areas where surface water is present or to intertidal areas below the mean high water mark. Drift and runofffrom treated areas may be hazardous to aquatic organisms in neighboring areas. Do not contaminate waterwhen disposing of equipment washwater/ dip solution. This product is highly toxic to bees exposed to directtreatment on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weedswhile bees are actively visiting the treated area.
13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Wastes resulting from the use of this product may be disposed of on site or at an EMPTY CONTAINER:
Triple rinse (or equivalent) and offer for recycling or reconditioning, or puncture and dispose of in a sanitarylandfill, or by other approved State and Local procedures.
If Empty:Do not reuse this container. Place in trash or offer for recycling if available. EVERCIDE® Permethrin 10% EC 2784
If Partly Filled:Call your local solid waste agency or 1-800-CLEAN-UP for disposal instructions. Never place unused productdown any indoor or outdoor drain.
RCRA/EPA WASTE INFORMATION: None of the ingredients in this product appear on the RCRA lists (40 CFR
261.24, 40CFR 251.33) or CERCLA Hazardous Substance list (40 CFR Part 302 Table 302.4)
14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Insecticides, Insect or Animal Repellent, Liquid, N.O.S. PRIMARY HAZARD CLASS/DIVISION: Non-Hazardous UN/NA NUMBER: N/A PACKING GROUP: N/A OTHER SHIPPING INFORMATION: This material is not regulated by DOT as a hazardous material when
shipped in Non-Bulk quantities (i.e., less than 119 Gallons / 450 Liters).
When shipping in Bulk-quantities (i.e., more than 119 Gallon's/ 450 Liter's), please contact MGK for theproper shipping description. AIR (ICAO/IATA) PROPER SHIPPING NAME: Insecticides, Insect or Animal Repellent, Liquid, N.O.S. PRIMARY HAZARD CLASS/DIVISION: Non-Hazardous UN/NA NUMBER: N/A PACKING GROUP: N/A VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Not Available 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: FIRE: YES PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: YES 313 REPORTABLE INGREDIENTS: 302/304 EMERGENCY PLANNING EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present
There are no components that are subject to emergency requirements under CERCLA Section103(a)(40 CFR 302.4) in this formulation. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control
Act's inventory reporting requirements. STATE REGULATIONS VOLATILE ORGANIC COMPOUNDS (VOC):
This product contains less than 52% VOC’s. EVERCIDE® Permethrin 10% EC 2784 16. OTHER INFORMATION REVISION SUMMARY Revision #: 2 This MSDS replaces the July 25, 2002 MSDS. Any changes in information
are as follows: In Section 1 Prepared By In Section 3 Emergency Overview - Immediate Concerns ChronicEffects Potential Heath Effects - Eyes Potential Health Effects - Skin Potential Health Effects - InhalationPotential Health Effects - Ingestion Medical Conditions Aggravated Target Organs In Section 4 Firstaid - EyesFirstaid - Ingestion Notes to Physician In Section 5 Flash Point °F (From) Flash Point °C (From) In Section 7Handling Storage In Section 8 Engineering Controls Skin Protection Eyes-Face Protection RespiratoryProtection Clothing Protection In Section 9 (pH) (From) (pH) (Group Field) for Water Solubility (Group Field) forDensity Specific Gravity (From) VOC (Unit) Specific Gravity Method Specific Gravity °C Viscosity (From)Viscosity (Unit) Viscosity °C (Group Field) for Percent Volatile (VOC) (wt%) (Operator) VOC (From) In Section10 Hazardous Decomposition Products In Section 11 Eye Effects Skin Effects Dermal LD50 (Operator) DermalLD50 Dermal LD50 (Value) Dermal LD50 (Unit) Oral LD50 Inhalation LC50 Reproduction ToxicologicalSensitization Oral LD50 (Value) Oral LD50 (Unit) Oral LD50 (Operator) In Section 12 Environmental DataEcotoxicological Information In Section 13 Empty Container RCRA/USPA Waste Information In Section 14 DOTPrimary Hazard Class/Division DOT UN/NA Number DOT Packing Group Reportable Quantity AIR ProperShipping Name AIR Primary Hazard Class/Division AIR Packing Group AIR UN/NA Number DOT_RQ_UNTNot Found In Section 15 Chronic SARA 313 Reportable Ingredients Regulations: State 302/304 EmergencyPlanning In Section 16 Section 16 Footnotes
HMIS RATING FLAMMABILITY: PHYSICAL HAZARD: PERSONAL PROTECTION: HMIS RATINGS NOTES: We assign HMIS ratings to this product based on the hazards of its ingredients(s).
Since the customer is most aware of the applications and conditions of use, he or she must ensure that theproper Personal Protective Equipment is provided, consistent with the information contained in Section's 7 and8 of this MSDS. COMMENTS: The data contained herein is based on information currently available to MGK Company, and
believed to be factual and the opinions expressed to be those of qualified experts; however, this data is not tobe taken as a warranty or representation for which MGK Company assumes legal responsibility.
(Cite as: 356 F.3d 1357) 168(2.1) SMITHKLINE BEECHAM CORP. (doing business asNarrowing amendment made by patent applicant to satisfyany requirement of Patent Act may give rise to estoppelwhen patentee subsequently asserting infringement under 168(2.1) Nos. 02-1581, 02-1612, 03-1011. presumption that patentee surrendered territory betweenoriginal claim and amended claim; such pre
(Note All mineral and vitamin research was done Purification Rundown Series 4 RESEARCH DATA ON NUTRITIONAL VITAMIN INCREASES ON THE PURIFICATION RUNDOWN THE PURIFICATION RUNDOWNREPLACES THE SWEAT PROGRAM(This data is released as a record of researches and resultsnoted. It cannot be construed as a recommendation of medicaltreatment or medication and it is undertaken by anyone on hisown
MATERIAL SAFETY DATA SHEET