Antislipdirect.co.uk

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
SAFETY DATA SHEET
9700 Coldmax Rapid™ - Base
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Product name
: 9700 Coldmax Rapid™ - Base
Product description
: Floorcoating. Paint.
Product type
: Liquid.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use
: Floorcoating. Paint.
1.3 Details of the supplier of the safety data sheet
Rust-Oleum Netherlands BV, PO. Box 138, NL-4700 AC Roosendaal, The Netherlands Martin Mathys NV, Kolenbergstraat 23, B-3545 Zelem, Belgium e-mail address of person
: [email protected]
responsible for this SDS
1.4 Emergency telephone number
Telephone number
: +44 (0) 207 858 1228
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
: Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification
Human health hazards
: May cause sensitisation by skin contact.
Environmental hazards
: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard symbol or symbols
Indication of danger
: Irritant
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SECTION 2: Hazards identification
Risk phrases
: R43- May cause sensitisation by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
Safety phrases
: S24- Avoid contact with skin.
S37- Wear suitable gloves.
S61- Avoid release to the environment. Refer to special instructions/safety datasheet.
Hazardous ingredients
: bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3-methylcyclohexyl)methane
tetraethylN,N’-(methylenedicyclohexane-4,1-diyl)bis-dl-aspartate Supplemental label
: Not applicable.
elements
Special packaging requirements
Containers to be fitted
: Not applicable.
with child-resistant
fastenings
Tactile warning of danger
: Not applicable.
2.3 Other hazards
Other hazards which do
: Not available.
not result in classification
SECTION 3: Composition/information on ingredients
Substance/mixture
: Mixture
Classification
Product/ingredient
Identifiers
67/548/EEC
Regulation (EC) No.
1272/2008 [CLP]
bis(ethoxycarbonyl)ethylamino)- 0000015937-58 methylcyclohexyl)methane CAS: 136210-32-7 Date of issue/Date of revision : 06-02-2013.
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SECTION 3: Composition/information on ingredients
See Section 16 for
See Section 16 for the
the full text of the R-
full text of the H
phrases declared
statements declared
There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have beenassigned a workplace exposure limit and hence require reporting in this section.
Type[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recoveryposition and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.
Skin contact
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion
: If swallowed, seek medical advice immediately and show the container or label. Keep
person warm and at rest. Do not induce vomiting.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or weargloves.
4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the preparation itself. The preparation has been assessed following the conventionalmethod of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. Seesections 3 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may resultin adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on thekidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscularweakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with thepreparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorptionthrough the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components fromshort-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3-methylcyclohexyl)methane, tetraethylN,N’-(methylenedicyclohexane-4,1-diyl)bis-dl-aspartate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, Pine Oil. May produce an allergic reaction.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment.
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SECTION 4: First aid measures
See toxicological information (Section 11) SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing
: Recommended: alcohol-resistant foam, CO2, powders, water spray.
Unsuitable extinguishing
: Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Hazards from the
: Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture
Hazardous thermal
: Decomposition products may include the following materials: carbon monoxide,
decomposition products
carbon dioxide, smoke, oxides of nitrogen.
5.3 Advice for firefighters
Special protective actions
: Cool closed containers exposed to fire with water. Do not release runoff from fire to
for fire-fighters
Special protective
: Appropriate breathing apparatus may be required.
equipment for fire-fighters
Additional information
: No unusual hazard if involved in a fire.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel
Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also Section 8 foradditional information on hygiene measures.
6.2 Environmental
: Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions
rivers, or sewers, inform the appropriate authorities in accordance with localregulations.
6.3 Methods and materials
: Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and
earth, vermiculite or diatomaceous earth and place in container for disposal cleaning up
according to local regulations (see section 13). Preferably clean with a detergent.
Avoid using solvents.
6.4 Reference to other
: See Section 1 for emergency contact information.
sections
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe
: Prevent the creation of flammable or explosive concentrations of vapours in air and
handling
avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights andother sources of ignition have been excluded. Electrical equipment should beprotected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receivingcontainer with bonding strap. Operators should wear antistatic footwear and clothingand floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or Date of issue/Date of revision : 06-02-2013.
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SECTION 7: Handling and storage
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws. Do not allow to enter drains or
watercourses.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.
7.2 Conditions for safe
: Store in accordance with local regulations.
storage, including any
Notes on joint storage
incompatibilities
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away
from heat and direct sunlight. Keep away from sources of ignition. No smoking.
Prevent unauthorised access. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Recommendations
: Not available.
Industrial sector specific
: Not available.
solutions
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Product/ingredient name
Exposure limit values
EH40/2005 WELs (United Kingdom (UK), 10/2007).
TWA: 125 mg/m³, (trimethylbenzene (25 ppm)) 8 hour(s).
Recommended monitoring
: If this product contains ingredients with exposure limits, personal, workplace
procedures
atmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.
Derived effect levels
Product/ingredient name
Exposure
Population
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SECTION 8: Exposure controls/personal protection
Predicted effect concentrations
Product/ingredient name
Compartment Detail
Method Detail
bis(ethoxycarbonyl)ethylamino)-3-methylcyclohexyl)methane methylenedicyclohexane-4,1-diyl)bis-dl-aspartate 8.2 Exposure controls
Appropriate engineering
: Provide adequate ventilation. Where reasonably practicable, this should be achieved
controls
by the use of local exhaust ventilation and good general extraction. If these are notsufficient to maintain concentrations of particulates and solvent vapours below theOEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Washcontaminated clothing before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location.
Eye/face protection
: Safety glasses with side shields. (EN166)
Skin protection
Hand protection
: Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
The user must check that the final choice of type of glove selected for handling thisproduct is the most appropriate and takes into account the particular conditions ofuse, as included in the user's risk assessment.
Body protection
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialistbefore handling this product. Recommended: Wear overalls or long sleeved shirt.
(EN 467) Other skin protection
: Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should beapproved by a specialist before handling this product.
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SECTION 8: Exposure controls/personal protection
Respiratory protection
: If workers are exposed to concentrations above the exposure limit, they must use
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dustand/or hazardous fumes. Wet sanding/flatting should be used wherever possible. Ifexposure cannot be avoided by the provision of local exhaust ventilation, suitablerespiratory protective equipment should be used.
Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.
Environmental exposure
: Do not allow to enter drains or watercourses.
controls
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
: Liquid.
: Various
: Not available.
Odour threshold
: Not available.
: Not available.
Melting point/freezing point
: Not available.
Initial boiling point and boiling : >200°C
range
Flash point
: Closed cup: >60°C
Evaporation rate
: Not available.
Flammability (solid, gas)
: Not available.
Burning time
: Not applicable.
Burning rate
: Not applicable.
Upper/lower flammability or
: Not available.
explosive limits
Vapour pressure
: Not available.
Vapour density
: Not available.
Relative density
Solubility(ies)
: Insoluble in the following materials: cold water and hot water.
Partition coefficient: n-
: Not available.
octanol/water
Auto-ignition temperature
: Not available.
Decomposition temperature
: Not available.
Viscosity
: Not available.
Explosive properties
: Not available.
Oxidising properties
: Not available.
9.2 Other information
SECTION 10: Stability and reactivity
10.1 Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
: Stable under recommended storage and handling conditions (see section 7).
10.3 Possibility of
: Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
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SECTION 10: Stability and reactivity
10.4 Conditions to avoid
: When exposed to high temperatures may produce hazardous decomposition
10.5 Incompatible materials
: Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous
: Under normal conditions of storage and use, hazardous decomposition products
decomposition products
should not be produced. If involved in a fire, toxic gases including CO, CO2 andsmoke can be generated.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
There are no data available on the preparation itself. The preparation has been assessed following the conventionalmethod of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. Seesections 3 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may resultin adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on thekidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscularweakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with thepreparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorptionthrough the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components fromshort-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3-methylcyclohexyl)methane, tetraethylN,N’-(methylenedicyclohexane-4,1-diyl)bis-dl-aspartate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, Pine Oil. May produce an allergic reaction.
Acute toxicity
Product/ingredient name
Exposure
hydrocarbons, aromatic, C9 LC50 Inhalation Vapour Conclusion/Summary
: Not available.
Irritation/Corrosion
Product/ingredient name
Exposure
Observation
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SECTION 11: Toxicological information
methylenedicyclohexane-4,1-diyl) bis-dl-aspartate Conclusion/Summary
: Not available.
Sensitisation
Product/ingredient name
exposure
3-methylcyclohexyl)methanetetraethylN,N’-( methylenedicyclohexane-4,1-diyl) bis-dl-aspartatehydrocarbons, aromatic, C9 Conclusion/Summary
: Not available.
Mutagenicity
Product/ingredient name
Experiment
Conclusion/Summary
: Not available.
Carcinogenicity
Conclusion/Summary
: Not available.
Reproductive toxicity
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SECTION 11: Toxicological information
Product/ingredient name
Maternal
Fertility Developmental
Exposure
toxicity
Conclusion/Summary
: Not available.
Teratogenicity
Conclusion/Summary
: Not available.
Other information
: Not available.
SECTION 12: Ecological information
12.1 Toxicity
There are no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.
Product/ingredient name
Exposure
methylenedicyclohexane-4,1-diyl) bis-dl-aspartate Daphnia spec. - Daphnia magna 48 hours- <24 hours Date of issue/Date of revision : 06-02-2013.
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SECTION 12: Ecological information
Conclusion/Summary
: Not available.
12.2 Persistence and degradability
Product/ingredient name
Inoculum
methylenedicyclohexane-4,1-diyl) bis-dl-aspartate Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
bis(ethoxycarbonyl)ethylamino)- Fresh water 1 days 3-methylcyclohexyl)methane Fresh water 0.7 daystetraethylN,N’-( 12.3 Bioaccumulative potential
Product/ingredient name
Potential
3-methylcyclohexyl)methanetetraethylN,N’-( methylenedicyclohexane-4,1-diyl) bis-dl-aspartatehydrocarbons, aromatic, C9 12.4 Mobility in soil
Soil/water partition
: Not available.
coefficient (KOC)
Mobility
: Not available.
12.5 Results of PBT and vPvB assessment
: Not applicable.
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SECTION 12: Ecological information
: Not applicable.
12.6 Other adverse effects
: No known significant effects or critical hazards.
SECTION 13: Disposal considerations
Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
13.1 Waste treatment methods
Methods of disposal
: The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the foulsewer but processed in a suitable effluent treatment plant. Dispose of surplus andnon-recyclable products via a licensed waste disposal contractor. Disposal of thisproduct, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.
Hazardous waste
European waste
: The European Waste Catalogue classification of this product, when disposed of as
catalogue (EWC)
waste, is:08 01 11* waste paint and varnish containing organic solvents or other dangeroussubstances.
If this product is mixed with other wastes, this code may no longer apply. If mixedwith other wastes, the appropriate code should be assigned. For further information,contact your local waste authority.
Packaging
Methods of disposal
: The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.
Special precautions
: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of spiltmaterial and runoff and contact with soil, waterways, drains and sewers.
SECTION 14: Transport information
14.1 UN number
14.2 UN proper
shipping name
14.3 Transport
hazard class(es)
14.4 Packing
Environmental
hazards
14.6 Special
Transport within
Transport within
Transport within
precautions for
user’s premises:
user’s premises:
user’s premises:
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SECTION 14: Transport information
the product know what the product know what the product know whatto do in the event of an to do in the event of an to do in the event of anaccident or spillage.
Additional
information
14.7 Transport in bulk
: Not available.
according to Annex II of
MARPOL 73/78 and the IBC
Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks,
as required by other health and safety legislation. The provisions of the national health and safety at work regulations
apply to the use of this product at work.
: 3824 90 70
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
Annex XVII - Restrictions
: Restricted to professional users.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
VOC for Ready-for-Use
: 2004/42/EC - IIA/j: 550g/l (2007) 500g/l (2010). <= 72g/l VOC.
Mixture
Europe inventory
: Not determined.
Black List Chemicals
: Not listed
Priority List Chemicals
: Not listed
Industrial use
: The information contained in this safety data sheet does not constitute the user’s
own assessment of workplace risks, as required by other health and safetylegislation. The provisions of the national health and safety at work regulations applyto the use of this product at work.
15.2 Chemical Safety
: This product contains substances for which Chemical Safety Assessments are still
Assessment
SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number Date of issue/Date of revision : 06-02-2013.
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SECTION 16: Other information
Full text of abbreviated H
statements
May be fatal if swallowed and enters airways.
May cause an allergic skin reaction.
May cause respiratory irritation. May cause drowsiness or dizziness.
Very toxic to aquatic life with long lasting effects.
Harmful to aquatic life with long lasting effects.
Full text of classifications
: Acute Tox. 4, H302
[CLP/GHS]
Aquatic Chronic 1, H410 AQUATIC TOXICITY (CHRONIC) - Category 1Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3Asp. Tox. 1, H304 EXPOSURE) [Respiratory tract irritation and Narcoticeffects] - Category 3 Full text of abbreviated R
: R10- Flammable.
R22- Harmful if swallowed.
R65- Harmful: may cause lung damage if swallowed.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R43- May cause sensitisation by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
Full text of classifications
: Xn - Harmful
[DSD/DPD]
Xi - IrritantN - Dangerous for the environment Date of printing
: 08-02-2013.
Date of issue/ Date of
: 06-02-2013.
revision
Date of previous issue
: No previous validation.
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.
Rust-Oleum Netherlands B.V. / Martin Mathys N.V.
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Source: http://www.antislipdirect.co.uk/pdf/MSDS_9700_BS-gb.pdf