Microsoft word - vanadyl acetyl acetonate msds ltd
MATERIAL SAFETY DATA SHEET
Section 1 - Product and Company Information Product Name VANADYL ACETYLACETONATE, Section 2 - Composition/Information on Ingredient
Substance Name
VANADYL ACETYLACETONATE 3153-26-2 Yes Formula (C5H8O2)2VO Section 3 - Hazards Identification EMERGENCY OVERVIEW Harmful. Harmful if swallowed. Irritating to eyes, respiratory system and skin. Target organ(s): Nerves. HMIS RATING HEALTH
For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. EYE EXPOSURE In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Cont.2. Regd. & Corporate Office : B-34, M.I.D.C., Badlapur (E). Dist. Thane, Maharashtra, India. Pin – 421503
Tel. : + 91-251-269 7340/ 269 0651 Fax : + 91 – 251 – 269 1572 / 269 7347
Email : [email protected] / [email protected] Web. : www.omkarchemicals.com
Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe dust. Avoid contact with eyes,skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. SPECIAL REQUIREMENTS Air sensitive. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143)respirator. Hand: Compatible chemical-resistant gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Appearance Physical State: Solid Form: Powder Property Value At Temperature or Pressure Molecular Weight 265.16 AMU pH N/A BP/BP Range N/A MP/MP Range 250 °C Freezing Point N/A Vapor Pressure N/A Vapor Density N/A Saturated Vapor Conc. N/A SG/Density N/A Bulk Density N/A Odor Threshold N/A Volatile% N/A VOC Content N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Surface Tension N/A Partition Coefficient
N/A = not available Section 10 - Stability and Reactivity STABILITY Stable: Stable. Conditions of Instability: May discolor on exposure to air. Conditions to Avoid: Air. Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Vanadium/vanadium oxides. Cont.3. Regd. & Corporate Office : B-34, M.I.D.C., Badlapur (E). Dist. Thane, Maharashtra, India. Pin – 421503
Tel. : + 91-251-269 7340/ 269 0651 Fax : + 91 – 251 – 269 1572 / 269 7347
Email : [email protected] / [email protected] Web. : www.omkarchemicals.com
HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur Section 11 - Toxicological Information ROUTE OF EXPOSURE Skin Contact: Causes skin irritation. Skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE May liberate 2,4-pentanedione upon decomposition. 2,4-Pentanedione has the following toxicological hazards: toxic, irritant, neurological hazard, teratogen, possible mutagen, target organ - thymus. In humans, 2,4-pentanedione is reported to cause contact dermatitis and contact urticaria. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 22-26-36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US CLASSIFICATION AND LABEL TEXT Indication of Danger: Harmful. Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US Statements: Target organ(s): Nerves. UNITED STATES REGULATORY INFORMATION Cont.4. Regd. & Corporate Office : B-34, M.I.D.C., Badlapur (E). Dist. Thane, Maharashtra, India. Pin – 421503
Tel. : + 91-251-269 7340/ 269 0651 Fax : + 91 – 251 – 269 1572 / 269 7347
Email : [email protected] / [email protected] Web. : www.omkarchemicals.com
SARA LISTED: Yes DEMINIMIS: 1 % NOTES: This product is subject to SARA section 313 reporting requirements. CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: No NDSL: Yes Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Omkar Speciality Chemicals Limited.,shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Regd. & Corporate Office : B-34, M.I.D.C., Badlapur (E). Dist. Thane, Maharashtra, India. Pin – 421503
Tel. : + 91-251-269 7340/ 269 0651 Fax : + 91 – 251 – 269 1572 / 269 7347
Email : [email protected] / [email protected] Web. : www.omkarchemicals.com
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